what about renaming the neverwinter nights 2 folder in mydocuments? after starting the game it will automatically recreate that folder. put your spells.2da in the override, start a new game (the tutorial modul should be fine), give the pc enough xp through dev console to level up and look what happens. this way you could be sure that there's no other file interfering.
*Hangs head in stupidity*
After following your advice, I double checked my folders again, because the override worked on a new nwn2 folder >_<
I can't believe I didn't see the spells.2da file in my teleportoverride folder 
Thank you all for the help lol
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