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[lespaul678]

Some of the mats for making a masterwork piece "claim" that you get a "30%" or "40%" chance at improving stats on that item, I have tried this one item, 15 times.  Either it's a bug or RNG REALLY hates me.

[flemethlol]

It is determined after creation of the item before it. It prevents save scumming.
Masterwork is not really 'worth' it tbh

Stuff like 'Gain 3 Guard, 5 Guard, Chain Lightning Proc, 1% Heal per hit is a better investment then like 2-3% more resistances and 40-60 more defence