Political Leaders: too lazy to count, but way more men than female. (the females I could only think of Celene, Briala, the Divine, Fiona and Calpernia. For the males it's basically everybody else. From Fairbanks, to all the generals in all armies you see in the game, to the Mayor of Crestwood, to Corpyhpeus)
are you really going to compare the mayor of a Ferelden backwater to the Empress of Orlais? Because then we are never going to get anywhere.
of the actually noteworthy political figures
The head of the Wardens in the South, the ruler of Orlais, the Divine and both of her hands, Calpernia, Fiona, Andraste, Anora, every Chantry mother, such as Giselle, and Briala
compared to Corypheus, Alistair, Gaspard, and Samson