My personal favorites for biotic explosions are Fury Adept and Awakened Collector.
Fury gets decent bonus for explosions from her skills and since she has both Annihilation Field and Dark Channel. both she can detonate with Throw.
with her fast recharge on skills you can just go crazy with throw and keep detonating things.
Collectors biotic detonations are more of a "cherry on a top" type. since he gets no bonus explosion damage, the explosions themselves aren't that impressive, however combining Dark Orb and Seeker Swarm for biotic detonations has quite good effect, for example i use the large AoE blast upgraded Dark Orb and 4 seeker swarms, doing this i can throw the orb on a room full of mobs, the orb kills all the trash mobs right away. ones with shields/barriers are left with about 50% - 75% life so they can be finished off by throwing a Seeker Swarm which causes a detonation and kills them.
as far as who has the strongest detonation however i'm not sure. i think you might just want to pick character best suited for your combat style.





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