I think the challenge should change to, "Defeat X enemies while they are poisoned" rather than, "Defeat X enemies using poison damage" (where the poison has to be what kills them). As of now, the only two means of killing an enemy with poison damage is Poison Weapons and Toxic Cloud. The former (Poisoned Weapons) is not going to register a majority of the time you strike, since the enemy would likely be killed by the weapon damage itself rather than the poison; or rune elemental damage if you have it equipped. The latter (Toxic Cloud) requires enemies to remain still inside of the cloud. Even with the upgrade, in general, poison damage ticks slowly and at relatively low level of damage (understandably). Getting Poison kills while playing with other players is incredibly difficult, and as of now, I'm basically grinding Routine solo just to complete the challenge; which I don't think should be the standard in getting it done.
I'm not saying it can't be done, but I can promise you that this is likely one of the few challenges that players leave till last in terms of combat.
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