I got "The Heart of Despair" which is a level 24 staff that has the unique effect of give 50% cold resistance and 50% physical damage resistance when equipped. It also has 80 weapon damage. Unfortunately, with no grip or blade slots it's just not worth using lategame if your goal is to do damage.
I also got the sigil of deathroot, and a sword called "Bolt" which is similar to the brand schematic except it has 100 more weapon damage and has a % chance to cast chain lightning on hit.
I'm currently soft resetting now to see if I get any schematics, so far no luck.
EDIT:
Got the Knight's Second schematic this way. Hilariously enough, if you sync it to the golden nug and then reload again you get to keep the schematic, which made me crack up.